@Book{610628437,
author="Torborg, Christian",
title="Application of novel phosphine ligands in palladium-catalyzed cross-coupling reactions",
year="2009",
abstract="This thesis describes the application of 2-phosphino-N-aryl-heterocycles as ligands in Pd-catalyzed CC, CN and CO bond forming reactions. Based on prior studies, 2-phosphino-N-arylindoles and -pyrrols were found to form efficient catalysts with Pd-salts in the Sonogashira coupling of (hetero)aryl bromides and the Pd-catalyzed monoarylation of ammonia. The novel imidazole-based phosphines were prepared after a modular synthesis and are stable towards air. They were employed in the Pd-catalyzed phenol synthesis, the Heck-Cassar coupling, and the Pd-catalyzed monoarylation of ammonia. Furthermore, mechanistic studies in the Pd-catalyzed hydroxylation were undertaken.",
note="vorgelegt von Christian Torborg",
note="Enth. 5 Beitr. aus versch. Ztschr",
note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0174-3&pdf",
url="http://rosdok.uni-rostock.de/file/rosdok_derivate_000000004073/Dissertation_Torborg_2009.pdf",
url="http://d-nb.info/999072188/34",
url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0174-3",
language="English"
}