@Book{604071264, author="Brennf{\"u}hrer, Anne", title="Palladium/di-1-adamantyl-n-butylphosphine-catalyzed carbonylation reactions", year="2008", abstract="Within this thesis several homogeneous palladium-catalyzed carbonylation reactions in the presence of carbon monoxide were investigated. In the course of our studies, the superior performance of the catalyst system palladium acetate/di-1-adamantyl-n-butylphosphine (cataCXium® A) in comparison to established palladium catalysts was demonstrated for both reductive carbonylations and alkoxycarbonylations of aryl and vinyl bromides. Hence, a variety of (hetero)aromatic aldehydes and carboxylic acid derivatives (esters, amides, acids) were successfully synthesized, among them novel biologically interesting indolylmaleimides. Furthermore, an efficient method for the synthesis of non-steroidal anti-inflammatory drugs such as ketoprofen and suprofen was developed.", note="Anne Brennf{\"u}hrer", note="Enth. 6 Beitr. aus versch. Ztschr", note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0110-5", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0110-5&pdf", url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0110-5", language="English" }