@Book{562031685,
author="Enthaler, Stephan",
title="New aspects in homogeneous hydrogenation: development of practical rhodium phosphine catalysts and environmentally benign iron catalysts",
year="2007",
abstract="This dissertation deals with the application of monodentate phosphine ligands in asymmetric hydrogenation of CC double bonds. The usefulness of rhodium catalysts containing phosphines based on the 4,5Dihydro3Hdinaphtho[2,1c;1,́2́e]phosphepine scaffold was demonstrated in the reduction of various prochiral substrates, since excellent enantioselectivities up to 96{\%} ee were achieved. Furthermore, the properties of ironbased catalysts were studied in the field of transfer hydrogenation. Here high catalyst activities up to 2500 h-1 were obtained in the reduction of ketones.",
note="vorgelegt von Stephan Enthaler",
note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2008",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7&pdf",
url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2008-0008-7",
language="English"
}