@Book{1986237281, author="Ahrens, Sebastian", title="Rational design and synthesis of phosphine ligands and their application in transition metal-catalyzed reactions", year="2025", address="Germany; Rostock", abstract="This work reports the development of novel ligand and catalyst systems for selected transition metal-catalyzed reactions. The synthesis of (benzo-)furylphosphine ligands enabled the development of highly efficient cobalt catalysts for the isomerization of allylamines to enamines. Furthermore, the developed ligands were successfully applied in the palladium-catalyzed telomerization of 1,3-butadiene. In addition, ruthenium-based catalyst systems enabling the selective deuterium labeling of pharmaceutically relevant 2-propylbenzimidazole derivatives are presented.", school="Universit{\"a}t Rostock", note="vorgelegt von Sebastian Ahrens", note="Enth{\"a}lt Zeitschriftenartikel", note="GutachterInnen: Matthias Beller (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Marko Hapke (Johannes Kepler Universit{\"a}t Linz) ; Malte Behrens (Christian-Albrechts-Universit{\"a}t zu Kiel)", note="Dissertation Universit{\"a}t Rostock 2026 Kumulative Dissertation", doi="10.18453/rosdok_id00005821", url="https://purl.uni-rostock.de/rosdok/id00005821", url="https://doi.org/10.18453/rosdok_id00005821", language="English" }