@Book{1984128272, author="Banda, Saikumar", title="New cycloadditions and deconjugative alkylations of $\alpha$,$\beta$-unsaturated ketones enabled by transition metal, phosphine and base catalysis", year="2025", address="Germany; Rostock", abstract="This dissertation develops novel catalytic methods for the functionalization of $\alpha$,$\beta$-unsaturated ketones through cycloaddition and deconjugative alkylation reactions using transition-metal, organophosphine, and Br{\o}nsted base catalysis. Efficient syntheses of polycyclic and spirocyclic heterocycles were achieved with high selectivity, broad substrate scope, and scalability. Mechanistic studies provided insights into catalyst-controlled reactivity, expanding synthetic strategies for medicinal and materials chemistry.", school="Universit{\"a}t Rostock", note="vorgelegt von Saikumar Banda", note="GutachterInnen: Malte Brasholz (Universit{\"a}t Rostock) ; Nina Sch{\"u}tzenmeister (Universit{\"a}t Marburg)", note="Dissertation Universit{\"a}t Rostock 2026", doi="10.18453/rosdok_id00005793", url="https://purl.uni-rostock.de/rosdok/id00005793", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005793-3", url="https://d-nb.info/142068647X/34", url="https://doi.org/10.18453/rosdok_id00005793", language="English" }