@Book{1976005590,
author="Nasrullah, Ayu Afiqah",
title="The  chemistry of cyanophosphide and phosphafluorene: insights into structure and reactivity",
year="2025",
address="Germany; Rostock",
abstract="This thesis explores low-valent phosphorus chemistry using sterically demanding terphenyl (DippTer) substituents. It establishes the cyanophosphide [DippTerPCN]$^-$ as a versatile platform, exhibiting the first P--CN/NC coordination isomerism upon O$_2$ oxidation and transfer reactivity to GeCl$_2$ (forming chlorogermylenes) and PCl$_3$/AsCl$_3$. A related DippTer-phosphafluorene enables Frustrated Lewis Pair (FLP) activation of terminal alkynes, yielding zwitterionic alkenyl phosphonium borates.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Ayu Afiqah Nasrullah",
note="Enth{\"a}lt Zeitschriftenartikel",
note="GutachterInnen: Christian Hering-Junghans (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Eszter Bar{\'a}th (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Rudolf Pietschnig (Institut f{\"u}r Chemie, Universit{\"a}t Kassel)",
note="Dissertation Universit{\"a}t Rostock 2025 Kumulative Dissertation",
doi="10.18453/rosdok_id00005658",
url="https://purl.uni-rostock.de/rosdok/id00005658",
url="https://doi.org/10.18453/rosdok_id00005658",
language="English"
}