@Book{1963633202, author="El-Sepelgy, Osama", title="Bio-inspired sustainable catalysis with base-metals and visible light", year="2025", address="Rostock", abstract="This thesis explores biomimetic catalytic systems inspired by metalloenzymes, utilizing ligand-to-metal charge transfer (LMCT) and metal-ligand cooperation (MLC) to enable efficient 3d-metal catalysis. By using earth-abundant metals, these approaches mimic enzymatic mechanisms where ligands actively participate in reactions. It covers cobalt catalysis for visible-light-induced radical desaturation and manganese pincer complexes for various redox transformations. The research integrates experimental and theoretical studies to optimize sustainable catalytic systems.", school="Universit{\"a}t Rostock", note="vorgelegt von Dr. Osama El-Sepelgy", note="Enth{\"a}lt Zeitschriftenartikel", note="GutachterInnen: Matthias Beller (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Lutz Ackermann (Georg-August-Universit{\"a}t G{\"o}ttingen) ; Armido Studer (Universit{\"a}t M{\"u}nster)", note="Habilitationsschrift Universit{\"a}t Rostock 2025 Kumulative Habilitationsschrift", doi="10.18453/rosdok_id00005152", url="https://purl.uni-rostock.de/rosdok/id00005152", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005152-3", url="https://d-nb.info/1393157084/34", url="https://doi.org/10.18453/rosdok_id00005152", language="English" }