@Book{1951031288,
author="Rosenboom, Jan",
title="Phosphorus-centered radicals and biradicals",
year="2024",
address="Rostock",
abstract="This thesis deals with the synthesis, reactivity and spectroscopic properties of P-centered mono- and biradicals. First, the addition of aldehydes to the biradical [{\textbullet}P($\mu$-NTer)2P{\textbullet}], a classical concerted reaction mechanism, was investigated and elucidated in detail. In contrast, radical reactivity for this molecule was observed during the addition of bromoalkanes to [{\textbullet}P($\mu$-NTer)2P{\textbullet}]. This led to the synthesis of the persistent, phosphorus-centered monoradical [{\textbullet}P($\mu$-NTer)2PEt], which could also be detected by EPR spectroscopy as an intermediate during the radical reaction mechanism proposed here. Based on the reaction of [{\textbullet}P($\mu$-NTer)2P{\textbullet}] with bromoalkanes, the bridging of two biradical units was finally achieved with a dibromoalkane. From this, a phosphorus-centered disbiradical was synthesized and its special electronic situation was elucidated by means of extensive EPR experiments and quantum chemical calculations.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Jan Christoph Lukas Rosenboom",
note="Enth{\"a}lt Zeitschriftenartikel",
note="GutachterInnen: Axel Schulz (Universit{\"a}t Rostock) ; Jan Weigand (TU Dresden) ; Christian M{\"u}ller (FU Berlin)",
note="Dissertation Universit{\"a}t Rostock 2024 Kumulative Dissertation",
doi="10.18453/rosdok_id00005096",
url="https://purl.uni-rostock.de/rosdok/id00005096",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005096-8",
url="https://d-nb.info/139044998X/34",
url="https://doi.org/10.18453/rosdok_id00005096",
language="English"
}