@Book{1931412952,
author="Li, Sihan",
title="Highly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienes",
year="2024",
address="Rostock",
abstract="The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Sihan Li",
note="Enth{\"a}lt Zeitschriftenartikel",
note="GutachterInnen: Torsten Beweries (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)",
note="Dissertation Universit{\"a}t Rostock 2024 Kumulative Dissertation",
doi="10.18453/rosdok_id00004877",
url="https://purl.uni-rostock.de/rosdok/id00004877",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004877-8",
url="https://d-nb.info/137315067X/34",
url="https://doi.org/10.18453/rosdok_id00004877",
language="English"
}