@Book{1930546645, author="Khomutetckaia, Aleksandra", title="Synthesis of polycyclic heteroaromatic hydrocarbons by C-H activation reactions: application of cycloisomerization and Pd-catalyzed cross-coupling reactions", year="2024", address="Rostock", abstract="This dissertation focusses on the development of new synthetic routes to polycyclic aromatic hydrocarbons containing five-, six-, and seven-membered heterocyclic rings and the characterisation of these novel compounds. The synthetic investigations were directed to the application of C-H activation reaction. In particular, Pd-catalyzed C-H activations as well as acid mediated cycloisomerization reaction of 2-alkynyl biaryl derivatives were employed as key ring-closing synthesis steps.", school="Universit{\"a}t Rostock", note="vorgelegt von Aleksandra Khomutetckaia", note="Enth{\"a}lt Zeitschriftenartikel", note="Zeitschriftennachweis: 1. Aleksandra Khomutetckaia, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Azadibenzo[a,e]pyrenes. European Journal of Organic Chemistry. 2024, e202301299. DOI: 10.1002/ejoc.202301299. Online ISSN:1099-0690. Print ISSN:1434-193X. 2. Aleksandra Khomutetckaia, Niels Hildebrandt, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Diindeno[1,2,3-cd:1,2,3-mn]pyrene and Two of Its Aza-Analogs. European Journal of Organic Chemistry. 2023, e20230110. DOI: 10.1002/ejoc.202301101. Online ISSN:1099-0690. Print ISSN:1434-193X. 3. Aleksandra Khomutetckaia, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Benzo[h]imidazo[1,2-a]quinolines and 1,2a-Diazadibenzo[cd,f]azulenes. The Journal of Organic Chemistry. 2023, 88, 7929--7939. DOI: 10.1021/acs.joc.2c02738. Online ISSN 1520-6904. 4. Erich Ammon, Aleksandra Khomutetckaia, Alexander Villinger, Peter Ehlers, Peter Langer. Serendipitous discovery of Pd-catalyzed intramolecular cyclization of ortho-bromo(hetero)aryl-substituted (hetero)aryl-1,2-diketones: Applications in the synthesis of carba- and heterocyclic benzoin derivatives. Tetrahedron. 2023, 135, 133335. DOI: 10.1016/j.tet.2023.133335. ISSN 0040-4020", note="GutachterInnen: Peter Langer (Universit{\"a}t Rostock) ; Thomas J.J. M{\"u}ller (Heinrich-Heine-Universit{\"a}t D{\"u}sseldorf)", note="Dissertation Universit{\"a}t Rostock 2024 Kumulative Dissertation", doi="10.18453/rosdok_id00004866", url="https://purl.uni-rostock.de/rosdok/id00004866", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004866-5", url="https://d-nb.info/1372071865/34", url="https://doi.org/10.18453/rosdok_id00004866", language="English" }