@Book{1892116170,
author="Cisneros, Sebastian",
title="Structure-reactivity relationships in heterogeneous catalytic CO2 hydrogenation to CH4 and CO on low loaded precious metal catalysts",
year="2023",
address="Rostock",
abstract="The production of CH4 and CO via CO2 hydrogenation was studied on catalysts with low precious metal loading. CO2 methanation was investigated on Ru/TiO2 und Ru/ZrO2 catalysts with Ru < 1 wt.{\%}. CO production was investigated on Au/ZrO2 and Au/TiO2 catalysts with < 0.1 wt.{\%} Au. Notably the most O-defective catalysts showed the highest rates. In-situ spectroscopic assessments revealed distinct electronic metal-support interactions induced by electron transfer from the defects to the supported metal entities. This effect is proposed as driver for the catalytic enhancement.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Sebastian Cisneros",
note="GutachterInnen: Angelika Br{\"u}ckner (Leibniz Institut f{\"u}r Katalyse e.V., Universit{\"a}t Rostock) ; J{\"u}rgen Behm (Institut f{\"u}r Theoretische Chemie, Universit{\"a}t Ulm)",
note="Dissertation Universit{\"a}t Rostock 2024",
doi="10.18453/rosdok_id00004614",
url="https://purl.uni-rostock.de/rosdok/id00004614",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004614-6",
url="https://d-nb.info/1334986525/34",
url="https://doi.org/10.18453/rosdok_id00004614",
language="English"
}