@Book{1845697952, author="Bourriquen, Florian Marwan", title="Hydrogen / deuterium exchange reactions: small variations for heavy changes", year="2022", address="Rostock", abstract="This dissertation reports the development of new catalytic methodologies for deuterium incorporation into organic molecules. In a first part, the use of a simple Lewis acid is reported for the isotopic labelling of electron-rich (hetero)arenes. Next, two heterogeneous catalysts are presented for the labelling of comparable compounds: a first-generation iron-based system and a follow-up work using manganese. Both materials are easily prepared and fully characterised. Additionally, investigations were performed to gain insight on the mechanisms.", school="Universit{\"a}t Rostock", note="vorgelegt von Florian Bourriquen", note="Year of oral defence: 2023", note="Enth{\"a}lt Zeitschriftenartikel", note="GutachterInnen: Matthias Beller (Leibniz-Institut f{\"u}r Katalyse e.V.) ; Manuel van Gemmeren (Christian-Albrechts-Universit{\"a}t zu Kiel)", note="Dissertation Universit{\"a}t Rostock 2023 Kumulative Dissertation", doi="10.18453/rosdok_id00004295", url="http://purl.uni-rostock.de/rosdok/id00004295", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004295-8", url="https://d-nb.info/1292078758/34", url="https://doi.org/10.18453/rosdok_id00004295", language="English" }