@Book{1831239965,
author="Kopf, Sara",
title="Development of hydrogen isotope exchange methodologies for the deuteration of aromatic substrates",
year="2022",
address="Rostock",
abstract="This thesis entails the development of practical and cost-efficient deuteration methodologies. The first C--H activation and deuteration of aromatic substrates using an earth-abundant manganese catalyst and transient directing groups was reported. Secondly, the transient directing group strategy was transferred to a ruthenium-catalyzed hydrogen isotope exchange reaction. Lastly, the electronic characteristics of pyridine derivatives were harnessed for a transition metal-free deuteration protocol. The results are expected to inspire future developments in sustainable hydrogen isotope exchange.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Sara Kopf",
note="Enth{\"a}lt Zeitschriftenartikel",
note="GutachterInnen: Matthias Beller (Leibniz-Institut f{\"u}r Katalyse e.V., Rostock) ; Gr{\'e}gory Pieters (CEA Paris-Saclay) ; Matthias Tamm (TU Braunschweig)",
note="Dissertation Universit{\"a}t Rostock 2022 Kumulative Dissertation",
doi="10.18453/rosdok_id00004135",
url="http://purl.uni-rostock.de/rosdok/id00004135",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004135-3",
url="https://d-nb.info/1293540013/34",
url="https://doi.org/10.18453/rosdok_id00004135",
language="English"
}