@Book{1727957962, author="Ha, Quan Luu Manh", title="Development of Ni catalysts with low metal content and improved stability in the dry reforming of methane to syngas", year="2019", address="Rostock", abstract="Catalysts with 2.5 wt{\%} Ni supported on MgO-Al2O3 were developed for CH4 dry reform-ing (DRM) that are stable at either mild (stoichiometric) or severe (CH4-rich) conditions. Solid materials were characterized with suitable methods. Catalysts with NiO-MgO-Al2O3 solid solution were active even at 500 {\textdegree}C. In stoichiometric DRM, Ni catalyst modified with La and citric acid reduced both Ni re-oxidation and agglomeration, preserving high activity over 160 h. Besides, proper support pre-treatment or adding Gd3+ both offered outstandingly coking-resistant Ni-based catalysts for CH4-rich DRM over 100 h.", school="Universit{\"a}t Rostock", note="vorgelegt von Quan Luu Manh Ha", note="GutacherInnen: Udo Kragl (Universit{\"a}t Rostock, Institut f{\"u}r Chemie, Abteilung Technische und Analytische Chemie) ; Martin Muhler (Ruhr-Universit{\"a}t Bochum, Lehrstuhl f{\"u}r Technische Chemie)", note="Dissertation Universit{\"a}t Rostock 2019", doi="10.18453/rosdok_id00002741", url="http://purl.uni-rostock.de/rosdok/id00002741", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002741-9", url="https://d-nb.info/1293660574/34", url="https://doi.org/10.18453/rosdok_id00002741", language="English" }