@Book{1727955498,
author="Adomeit, Sven",
title="Structure-reactivity relationships in Cu/TEMPO catalyzed aerobic alcohol oxidation: mechanistic assessment by (coupled) operando spectroscopic tools",
year="2019",
address="Rostock",
abstract="Aerobic alcohol oxidation is a route to convert alcohols into aldehydes using homogenous Cu catalysts with O2 as the terminal oxidant. It is well-known that the Cu catalyst forms a Cu(I/II) shuttle during the reaction. To investigate still open issues coupled operando EPR/UV-vis/ATR-IR was used in a first step. Through this combination it was possible to observe distinctive effects of the structure and molar ratios of ligands/additives upon the redox behavior of the Cu(I/II) shuttle. The triple coupling was further developed into a 4-in-1 set-up by implementing X-ray absorption spectroscopy.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Sven Adomeit",
note="GutacherInnen: Angelika Br{\"u}ckner (Universit{\"a}t Rostock, Leibniz-Institut f{\"u}r Katalyse e.V.) ;  Felix Tuczek (Christian-Albrechts-Universit{\"a}t zu Kiel, Institut f{\"u}r Anorganische Chemie)",
note="Dissertation Universit{\"a}t Rostock 2019",
doi="10.18453/rosdok_id00002740",
url="http://purl.uni-rostock.de/rosdok/id00002740",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002740-2",
url="https://d-nb.info/1293660558/34",
url="https://doi.org/10.18453/rosdok_id00002740",
language="English"
}