@Book{1048999467, author="Wo{\'{z}}niak, Bartosz", title="Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate", year="2018", address="Rostock", abstract="This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.", school="Universit{\"a}t Rostock", note="vorgelegt von Bartosz Wozniak", note="Die Dissertation enth{\"a}lt Zeitschriftenartikel", note="Dissertation Universit{\"a}t Rostock 2019", doi="10.18453/rosdok_id00002403", url="http://purl.uni-rostock.de/rosdok/id00002403", url="https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002403-7", url="https://d-nb.info/1293655481/34", url="https://doi.org/10.18453/rosdok_id00002403", language="English" }