@Book{1042181462,
author="Puylaert, Pim",
title="Alternatives to phosphorus‐containing pincer ligands in catalytic hydrogenation",
year="2018",
address="Rostock",
abstract="The development of alternatives to phosphine-containing pincer ligands for homogeneous hydrogenation is described. Ligands of the ``NNS'' type and their Ru- and Co-complexes were synthesised, characterised, and successfully applied in chemoselective hydrogenations. Complexes of the type RuCl2(NNS)(PPh3) selectively hydrogenated unsaturated aldehydes, ketones and esters. Cobalt complexes CoCl2(NNS), in contrast, were precursors for nanoparticles which selectively hydrogenated olefins. Additionally, the Trost ligand was used for the first time in the asymmetric hydrogenation of ketones.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Pim Puylaert",
note="Published manuscripts and the corresponding supporting information available online: 1) P. Puylaert, R. van Heck, Y. Fan, A. Spannenberg, W. Baumann, M. Beller, J. Medlock, W. Bonrath, L. Lefort, S. Hinze, J.G. de Vries, Chemistry ‐ A European Journal 2017, 23, 8473‐8481, DOI: 10.1002/chem.201700806 2) B.M. Stadler, P. Puylaert, J. Diekamp, R. van Heck, Y. Fan, A. Spannenberg, S. Hinze, J.G. de Vries, Advanced Synthesis and Catalysis 2018, 260, 1151‐1158, DOI: 10.1002/adsc.201701607 3) M. Cettolin, P. Puylaert, L. Pignataro, S. Hinze, C. Gennari, J. G. de Vries, ChemCatChem 2017, 9, 3125‐3130, DOI: 10.1002/cctc.201700545. The fourth manuscript included in the dissertation has since been accepted for publication and is accessible online: 4) P. Puylaert, A. Dell'Acqua, F. El Ouahabi, A. Spannenberg, T. Roisnel, L. Lefort, S. Tin, J. G. de Vries, Catalysis Science {\&} Technology, 2019, Advance Article, DOI 10.1039/C8CY02218F",
note="Dissertation Universit{\"a}t Rostock 2018",
doi="10.18453/rosdok_id00002357",
url="http://purl.uni-rostock.de/rosdok/id00002357",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0184-0",
url="https://d-nb.info/1293654426/34",
url="https://doi.org/10.18453/rosdok_id00002357",
language="English"
}