@Book{1042003475, author="Jaime Trevi{\~{n}}o, Diego Alberto", title="Selective oxidation of C16 macrocyclic diene to epoxides and ketones", year="2017", address="Rostock", abstract="In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.", school="Universit{\"a}t Rostock", note="vorgelegt von Lic. Diego A. Jaime Trevin̂o", note="Dissertation Universit{\"a}t Rostock 2017", doi="10.18453/rosdok_id00002353", url="http://purl.uni-rostock.de/rosdok/id00002353", url="https://doi.org/10.18453/rosdok_id00002353", language="English" }