@Book{1026618800,
author="Xia, Tian",
title="Isomerization of allylic alcohols to the ketones catalyzed by first-row transition metal pincer complexes",
year="2018",
address="Rostock",
abstract="This thesis mainly describes the isomerization of allylic and homo-allylic alcohols to the corresponding carbonyl compounds in the presence of inexpensive transition metal complexes. [Fe(PNP)(CO)HCl] (PNP=di-(2-diisopropylphosphanyl-ethyl)amine), activated in situ with KOtBu, is a highly active catalyst for the isomerization of allylic and homo-allylic alcohols to ketones without an external hydrogen supply. High reaction rates were obtained at 80 oC, but the catalyst is also sufficiently active at room temperature with most substrates.<eng>",
school="Universit{\"a}t Rostock",
note="vorgelegt von Tian Xia",
note="Dissertation Universit{\"a}t Rostock 2018",
doi="10.18453/rosdok_id00002267",
url="http://purl.uni-rostock.de/rosdok/id00002267",
url="https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0103-8",
url="https://d-nb.info/1293652946/34",
url="https://doi.org/10.18453/rosdok_id00002267",
language="English"
}